Chemistry Help!! Thermodynamics
Posted: Sat Jun 08, 2013 11:00 am
Estimate the difference in energy produced when we burn 1kg of carbon vs producing nuclear energy from 1kg of U-235.
C + O2(g) -> CO2(g)
I have this:
U-235
Specific Heat Capacity of Carbon is 0.710 J/kgK
1kg Carbon = 1000kg /12g C/1moleC = 83.26 moles C
Amount of heat released when 1 kg of C is burned:
0.710kJ/mol x 83.26 moles C/1mole C = 59.1146 kJ
1kg of C releases 59.1146 kJ
1 kg Uranium-235 = 0.12 J/kgK = specific heat capacity of U
1 kg Uranium 1000kg/238g U/1mole U = 4.20 moles U
0.12kJ/mol x 4.20 moles U/1mole U = .504 kJ
1kg of U releases .504 kJ
U235 + n --> fission + 2 or 3 n + 200 MeV
1MeV (million electron volts) = 1.609 x 10^-13 j this corresponds to 3.2 x 10^-11 j
4.20 moles CO2 x 6.022x10^23 molecules/1mole CO2 molecules = 2.52x10^24
3.2x10^-11 J / 2.52x10^24 J = 1.269x10^13
The fission process releases over 12 trillion times more energy per kg of fuel.
My teacher said that I did something wrong here (J/mol conversion for Carbon and Uranium235) also I have the wrong value for 1kg of U since it releases more heat than 0.504kJ. Then recalculate. I need help very very detailed step by step help. PLEASE!
C + O2(g) -> CO2(g)
I have this:
U-235
Specific Heat Capacity of Carbon is 0.710 J/kgK
1kg Carbon = 1000kg /12g C/1moleC = 83.26 moles C
Amount of heat released when 1 kg of C is burned:
0.710kJ/mol x 83.26 moles C/1mole C = 59.1146 kJ
1kg of C releases 59.1146 kJ
1 kg Uranium-235 = 0.12 J/kgK = specific heat capacity of U
1 kg Uranium 1000kg/238g U/1mole U = 4.20 moles U
0.12kJ/mol x 4.20 moles U/1mole U = .504 kJ
1kg of U releases .504 kJ
U235 + n --> fission + 2 or 3 n + 200 MeV
1MeV (million electron volts) = 1.609 x 10^-13 j this corresponds to 3.2 x 10^-11 j
4.20 moles CO2 x 6.022x10^23 molecules/1mole CO2 molecules = 2.52x10^24
3.2x10^-11 J / 2.52x10^24 J = 1.269x10^13
The fission process releases over 12 trillion times more energy per kg of fuel.
My teacher said that I did something wrong here (J/mol conversion for Carbon and Uranium235) also I have the wrong value for 1kg of U since it releases more heat than 0.504kJ. Then recalculate. I need help very very detailed step by step help. PLEASE!