Hello Again,
I did some reading on the web regarding mirrors. Sorry to say I have not found a site that explains your question well. The following is a highly technical paper that talks about mirrors:
http://www.oriel.com/down/pdf/12010.pdf
The basic facts about how a mirror works/ages:
- As this paper says, every surface reflects light. Mirrors are just good at it
For mirrors, light gets reflected from the thin highly polished metal surface attached to the back of the glass. The metal used is typically silver, but one could use gold, aluminum, copper or others.
- Metals used in mirrors tarnish with time. When the metal tarnishes, its reflectivity (amout a light that it reflects) decreases. To protect the metal from tarnishing, a protective coating is applied. This slows down the oxidation process. Factors like high humidity, type of protective coating, metal used and others will affect the tarnishing (by oxidation) time.
Now, I think in the candle test; the yellow light reflected from old mirrors is caused by this drop in reflectivity. To measure reflectivity, one has to measure the amount of light reflected from the mirror and divided it by the amount of light going into it.
Hope this helps, If you have any follow up questions just let us know.