Magnesium Sulfate for Phosphate Buffer??

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pears123
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Joined: Thu Nov 27, 2014 8:51 am
Occupation: Student- 10th Grade
Project Question: I was looking at your "Water to Fuel to Water" Experiment in the chemistry section of your Project Ideas. I was wondering, would the experiment function if the 0.1 M phosphate buffer solution was replaced with a magnesium sulfate hepta-hydrate solution? If not, why?
Project Due Date: December 6th, 2014
Project Status: I am just starting

Magnesium Sulfate for Phosphate Buffer??

Post by pears123 »

Hello I am doing the "Water to Fuel to Water" Experiment under your chemistry category and I was wondering if the 0.1 M Phosphate Buffer can be substituted for a magnesium-sulfate hepta-hydrate solution? If not, why? Thanks for the help!
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Re: Magnesium Sulfate for Phosphate Buffer??

Post by deleted-2131 »

Hi pears123,

Unfortunately, no, you won't get good results if you use MgSO4-6H2O instead of the buffer described. Acid-base buffers require having conjugate weak acid-base pairs (in fairly large quantities) with appropriate acid dissociation constants to keep pH at the desired value. MgSO4-6H2O doesn't meet those requirements. Check out this webpage, which gives a very nice overview of how acid-base buffers work: http://chemwiki.ucdavis.edu/Physical_Ch ... es/Buffers. If you've had a chemistry class in high school, you should be able to follow what the webpage describes.
All the best,
Terik
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