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It's Raining, It's Pouring: Chemical Analysis of Rainwater

Abstract

Here is an interesting project that could be approached from several different scientific angles: Environmental Science, Weather & Atmosphere, Chemistry, or Plant Biology. You can probably think of your own variations to emphasize the scientific area that most interests you.

Summary

Areas of Science
Difficulty
 
Time Required
Very Long (1+ months)
Prerequisites
Must be familiar with titration or be able to learn how titration is used in this experiment
Material Availability
Readily available
Cost
Low ($20 - $50)
Safety
No issues
Credits

Andrew Olson, Ph.D., Science Buddies

Sources

This project was based on:

Objective

The goal of this project is to assess the water quality of rainwater collected from different geographical areas. The water quality measures used in this project are hardness, pH, and plant growth. Additional measures could be chosen to expand this project.

Introduction

Is the chemistry of rainwater from different geographical regions similar or different? How does rainwater chemistry relate to that of local surface water? How is rainwater chemistry affected by large-scale weather patterns? Does rainwater chemistry affect the growth of plants? These are some of the many questions you could choose to pursue with this project.

This project is based on Jonathan Allison's 2003 California State Science Fair entry. Here is how Jonathan summarized his experimental procedure: "I contacted friends and family from 11 different cities in the United States and asked them if they could help me by collecting rainwater from their city. After they collected it, they shipped it back to me. Then I tested the rainwater for hardness, using the chemical process of titration. Next I tested the rainwater for pH levels. Then I planted radish seeds in potting soil and watered each set of seedlings with rainwater from a different city. I observed, measured and recorded any growth or changes daily for seven days." (Allison, 2003)

Water Hardness

Water hardness is a measure of dissolved compounds (e.g., magnesium carbonate, calcium carbonate) in the water. These compounds can precipitate out in boilers and water heaters (scaling). Hard water makes less suds with soap and detergent, so you need to use more soap and detergent to get clothes and dishes clean with hard water. General guidelines for classification of waters are: 0 to 60 mg/L (milligrams per liter) as calcium carbonate is classified as soft; 61 to 120 mg/L as moderately hard; 121 to 180 mg/L as hard; and more than 180 mg/L as very hard (USGS, date unknown).

Figures 1 and 2 show USGS water hardness data for the continental United States. Figure 1 is a histogram showing the mean hardness data for each of the 344 stations sampled. Figure 2 is a map of the U.S., showing the regional patterns of groundwater hardness. In both cases, the data is from 1975, but the patterns shown have proven to be stable over time.

Histogram measuring the average level of groundwater hardness in different United States collection stations

Chart showing water hardness from 344 collection stations across the United States in 1975. Approximately 90 stations had soft water conditions, while 70 stations were moderately hard, 45 were hard, and the remaining 139 were very hard. 7 stations reported values of over 1.120 milligrams of calcium carbonate per liter which was the hardest level reported.


Figure 1. Histogram of U.S. groundwater hardness from 344 collection stations (USGS, 1975 data).
Map of the United States color coded to show groundwater hardness from collection stations across the entire country

Map showing water hardness from 344 collection stations across the United States in 1975. The groundwater hardness levels are elevated to above 151 mg/l in the mid-west region of the continental United States reaching from the northern most areas of North Dakota to the southrn most tip of Texas and extending west until the southern tip of California. Both the west and east coast are below 120 and 50 mg/l for water hardness with the bulk of the states with soft water stretching from northern Maine to southern Louisiana and to the east until northern Florida.


Figure 2. Map of U.S. groundwater hardness from 344 collection stations (USGS, 1975 data).

pH

Acidity and alkalinity are measured with a logarithmic scale called pH. pH is the negative logarithm of the hydrogen ion concentration:

pH = −log [H+] .

What this equation means is for each 1-unit change in pH, the hydrogen ion concentration changes ten-fold. Pure water has a neutral pH of 7. pH values lower than 7 are acidic, and pH values higher than 7 are alkaline (basic). Table 1 has examples of substances with different pH values (Decelles, 2002; Environment Canada, 2002; EPA, date unknown).

pH Value H+ Concentration
Relative to Pure Water
Example
0 10 000 000 battery acid
1 1 000 000 sulfuric acid
2 100 000 lemon juice, vinegar
3 10 000 orange juice, soda
4 1 000 tomato juice, acid rain
5 100 black coffee, bananas
6 10 urine, milk
7 1 pure water
8 0.1 sea water, eggs
9 0.01 baking soda
10 0.001 Great Salt Lake, milk of magnesia
11 0.000 1 ammonia solution
12 0.000 01 soapy water
13 0.000 001 bleach, oven cleaner
14 0.000 000 1 liquid drain cleaner
Table 1. The pH Scale: Some Examples

Figure 3 shows a map of the average pH of precipitation in the continental U.S. for the year 1992. "The areas of greatest acidity (lowest pH values) are located in the Northeastern United States. This pattern of high acidity is caused by the large number of cities, the dense population, and the concentration of power and industrial plants in the Northeast. In addition, the prevailing wind direction brings storms and pollution to the Northeast from the Midwest, and dust from the soil and rocks in the Northeastern United States is less likely to neutralize acidity in the rain." (USGS, 1997)

Map of the continental United States color coded to show average acidity of rainfall across the country

The data from 1992 shows that the highest acidity rain, with a pH as low as 4.1, falls in the northeastern section of the United States over the states of Ohio, Pennsylvania, and New York. However, almost the entirety of the western United States is prone to less acidic rain with a pH of greater than 5.5.


Figure 3. Map of U.S. annual average precipitation pH for 1992. (USGS, 1997).

Plant Growth

Most plants prefer soil that is near neutral pH. There are particular varieties (strawberries, azaleas and rhododendrons, for example) that prefer acidic soil. Soil pH also influences how readily available many soil nutrients are to plants.

Terms and Concepts

To do this project, you should do research that enables you to understand the following terms and concepts:

More advanced students will also want to understand the following terms and concepts:

Bibliography

  • Wikipedia contributors, 2006. Titration, Wikipedia, The Free Encyclopedia. Retrieved May 9, 2006.
  • These USGS webpages have information on patterns of water hardness of rivers and acidity in rainwater across the United States.
  • Reference on the pH scale:
  • Review pages on moles:
    The ChemTeam, (n.d.). The Mole Table of Contents. A Tutorial for High School Chemistry. Retrieved July 15, 2021.

Materials and Equipment

Disclaimer: Science Buddies participates in affiliate programs with Home Science Tools, Amazon.com, Carolina Biological, and Jameco Electronics. Proceeds from the affiliate programs help support Science Buddies, a 501(c)(3) public charity, and keep our resources free for everyone. Our top priority is student learning. If you have any comments (positive or negative) related to purchases you've made for science projects from recommendations on our site, please let us know. Write to us at scibuddy@sciencebuddies.org.

Experimental Procedure

  1. For the water hardness and pH tests, follow the instructions that come with the water test kit. When titrating samples, it is important to mix the solution well after each drop of test solution is added.
  2. For the plant growth portion of the experiment, it is important to keep all of the other growth conditions (sun exposure, soil, temperature, etc.) constant, and to vary only the source of water used for the plants. Be sure to use the same amount of water. Consult the Science Buddies resource, Measuring Plant Growth for methods you can use to quantify differences in growth.
icon scientific method

Ask an Expert

Do you have specific questions about your science project? Our team of volunteer scientists can help. Our Experts won't do the work for you, but they will make suggestions, offer guidance, and help you troubleshoot.

Variations

  • Does rainwater chemistry in your area vary with weather patterns? Collect samples over several weeks or months, and test the water quality. Keep track of the weather systems that produced the precipitation. Were there variations in the ultimate source of the moisture? Can you correlate these variations with changes in rainwater chemistry?
  • If you live in an urban area, is rainwater chemistry affected by smog? Check the air quality reported in the newspaper for the days that samples were collected. Do you see differences in rainwater chemistry after days with high smog compared to days with cleaner air?
  • For the samples in your study, how does rainwater hardness compare with groundwater hardness? (See Figure 2 in the Introduction, above.) How does the acidity compare to the 1992 U.S. data? (See Figure 3 in the Introduction, above.)
  • Here is a related Science Buddies project you might want to check out:

Careers

If you like this project, you might enjoy exploring these related careers:

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General citation information is provided here. Be sure to check the formatting, including capitalization, for the method you are using and update your citation, as needed.

MLA Style

Science Buddies Staff. "It's Raining, It's Pouring: Chemical Analysis of Rainwater." Science Buddies, 16 July 2021, https://www.sciencebuddies.org/science-fair-projects/project-ideas/EnvSci_p015/environmental-science/chemical-analysis-of-rainwater?from=Blog. Accessed 29 June 2022.

APA Style

Science Buddies Staff. (2021, July 16). It's Raining, It's Pouring: Chemical Analysis of Rainwater. Retrieved from https://www.sciencebuddies.org/science-fair-projects/project-ideas/EnvSci_p015/environmental-science/chemical-analysis-of-rainwater?from=Blog


Last edit date: 2021-07-16
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